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PPG elastomer |
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PPG elastomer prepared with PPG diols containing low amounts of
unsaturation give superior properties and enhanced mechanical
properties. |
Elastomer |
Prepolymer
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Polypropylene glycol 2000 MW (CAS # 25322-69-4
)
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100 |
100 |
100 |
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MDI recrystallized (CAS # 101-68-8) |
27.7
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47.7 |
75 |
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Prepolymer properties |
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NCO/OH |
2.2
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3.8 |
6.0
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NCO, % |
4.0
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8.0
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12 |
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MW prepolymer, avg |
2100
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1050
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700 |
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Viscosity, 20ºC, cps |
25,000
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7,500
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3,300 |
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Elastomer
preparation |
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Chain extender 1.4-butanediol (CAS # 110-63-4)
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5.4
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12.6
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22.4
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Catalyst Dibutyltin dilaurate (CAS # 77-58-7)
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25-50 ppm
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25-50 ppm
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25-50 ppm
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Potlife, minutes |
1-3
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1-3 |
1-3 |
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Demold time, minutes |
25
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35 |
70 |
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Hardness, Shore |
57A
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80A |
97A |
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Modulus 100 %, psi, (MPa)
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200(1.4)
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830(5.7)
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1690(11.7)
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300 %, psi, (MPa) |
360(2.5)
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1500(10.3)
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2230(15.4)
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Tensile Strength, psi, (MPa)
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2300(15.9)
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3800(26.2)
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3400(23.4)
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Elongation, %
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810
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700
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580
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Die C Tear, pli, (kNm)
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150(26)
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420(74)
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610(107)
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DBTDL catalyst has to be adjusted for cure
response, DBTDL can be replaced with a Bismuth
catalyst
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Last edited on:
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November 16, 2006
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